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So I was just on a discussion on Facebook and I got debating whether or not Observation Haki would be capable of detecting the invisible Shinigami from Bleach. I am not deciding who would win in a fight, but can Haki help locate a Shinigami?
As we see in this scan right here...

Usopp's first use of Observation Haki.
Usopp's first attempt at using Observation Haki allowed him to perfectly identify and locate Luffy and Law who were miles away and atop an large mountain, far from Usopp's eyesight. Keep in mind, this was Usopp's first time using Observation Haki, compare that with Luffy who trained for 2 years with a master Haki user to perfect his own Haki.
Shinigami are within the physical realm, they only remain remain invisible to normal people.
So what I'm basically asking is...

As we see in this scan right here...

Usopp's first use of Observation Haki.
Usopp's first attempt at using Observation Haki allowed him to perfectly identify and locate Luffy and Law who were miles away and atop an large mountain, far from Usopp's eyesight. Keep in mind, this was Usopp's first time using Observation Haki, compare that with Luffy who trained for 2 years with a master Haki user to perfect his own Haki.
Shinigami are within the physical realm, they only remain remain invisible to normal people.
So what I'm basically asking is...
